Triangulation parameters are not stored within STEP file, so that these manipulations in FreeCAD has no effect on produced STEP. What you want is probably adjusting triangulation parameters in CADRays. However, this application doesn't expose these parameters to user interface.
But CADRays is based on Draw Harness, so that you may follow it's official documentation to make more things, if you are not afraid of console input. For instance, command vdefaults could be used to change default meshing parameters (`vdefaults -angDefl 10` to change angular deflection to 10 degrees instead of default 20; you'll need re-importing model afterwards or redisplaying it 3D viewer) or command `incmesh` combined with `vdefaults -autoTriang 0` for tuning more meshing parameters.
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